Gold Toner (GP-1)

Gold Toner (GP-1) is Kodak's gold-thiocyanate toner formula — provides archival permanence enhancement comparable to selenium toning, plus a distinctive cool-blue color shift on most B&W silver-gelatin papers. Gold toning was Kodak's original archival recommendation in the early 20th century, predating the rise of selenium toning; GP-1 remains in occasional use today for the specific cool-blue aesthetic and as an archival alternative when selenium isn't available.
Key features
- Gold chloride + sodium thiocyanate + sodium chloride + sodium acetate chemistry
- Cool-blue color shift — distinctive on chlorobromide and bromide papers
- Archival enhancement comparable to selenium (both are silver → noble-metal-conversion mechanisms)
- Significantly more expensive than KRST due to gold chloride cost
- Single-bath process (no separate bleach step)
Workflow
- Print → develop → stop → fix → wash thoroughly (HCA recommended)
- Toning bath: 5-15 min in GP-1 working solution at 20°C; watch for cool-blue shift in highlights first
- Final wash: 30+ min running water for archival residual-thiosulfate levels
Practical notes
- Choose GP-1 over KRST when you want the cool-blue aesthetic with archival benefit
- Choose KRST when archival benefit is the priority and you want minimum visual shift
- Gold chloride costs $200+ per gram — GP-1 is the most expensive toner in routine use
- Working bath capacity ~20-30 8x10 prints per liter
- Stock keeps 6+ months sealed
- Compatible with most papers — but test on a sacrificial print first as some papers respond more dramatically than others
- PPE: nitrile gloves; gold chloride is moderately toxic
Related recipes
- [[recipe-krst|Kodak Rapid Selenium Toner]] — alternative archival toner with subtle warm shift
- [[recipe-sepia-toner|Sepia Toner]] — dramatic warm alternative; less archival benefit
- [[recipe-blue-toner-iron|Blue Toner (Iron)]] — non-archival blue alternative for color only
Mixing Instructions
Stock solution: Dissolve 1 g gold chloride in 1 liter of water at 20 °C.
Working solution:
- Take 125 ml of gold stock.
- Add 10 g sodium thiocyanate dissolved in 125 ml water.
- Add water to make 1 liter.
The solution should be slightly yellowish.
Toning:
- Prints must be thoroughly washed before toning.
- Immerse prints and agitate gently for 10-20 minutes.
- Check progress under white light — the shift to blue-cool tones is subtle.
Gold toner is expensive but the working solution can be reused until exhausted.
Ingredients for 1L of Working Solution
Volume:
ml
| # | Chemical | Role | Qty (1L) | Unit | Note |
|---|---|---|---|---|---|
| 1 | Gold Chloride | Toner | 1.0 | g | |
| 2 | Sodium Thiosulfate | Fixing Agent | 10.0 | g |