Classic Cyanotype

Alternative ProcessWorking Solution
Sir John Herschel (1842)Dilution: 1:1 (Solution A:B)
Classic Cyanotype
Image: Anna AtkinsPublic domain

The original cyanotype process, invented by Sir John Herschel in 1842.[1] Two solutions — ferric ammonium citrate (Solution A) and potassium ferricyanide (Solution B) — are mixed, coated onto paper, dried, and contact-printed under UV light. Exposed iron salts reduce from ferric to ferrous, forming Prussian blue (ferric ferrocyanide) upon washing. The result is a permanent blue image with a characteristic cyan tone. Simple, inexpensive, and forgiving — an ideal entry point for alternative processes.[2]

References

  1. BOOK Ware, Mike. Cyanotype: The History, Science and Art of Photographic Printing in Prussian Blue 1st ed. NMSI Trading Ltd (Science Museum), 1999. ISBN 1-900747-07-3.
  2. BOOK Crawford, William. The Keepers of Light: A History and Working Guide to Early Photographic Processes 1st ed. Morgan & Morgan, 1979. ISBN 0-87100-158-6.

Mixing Instructions

Solution A: Dissolve 25 g ferric ammonium citrate (green) in 100 ml distilled water at 20 °C.

Solution B: Dissolve 10 g potassium ferricyanide in 100 ml distilled water at 20 °C.

Store each solution separately in brown glass bottles — they keep for months individually.

To sensitize and print:

  1. Mix equal parts A and B immediately before use.
  2. Coat onto paper with a brush or glass rod under dim incandescent light (not fluorescent/UV).
  3. Dry completely in the dark.
  4. Expose under UV light (sun or UV lamp).
  5. Develop in running water for 5-10 minutes.

Ingredients for 1L of Working Solution

Volume:
ml
#ChemicalRoleQty (1L)UnitNote
1Ferric Ammonium CitrateToner250.0g(Solution A)
2Potassium FerricyanideToner100.0g(Solution B)